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Current Question (ID: 7988)

Question:
The correct increasing order of ionic character of the following molecule is: $\text{LiF, K}_2\text{O, N}_2\text{, SO}_2\text{, ClF}_3$
Options:
  • 1. $1.\ \text{N}_2 < \text{SO}_2 < \text{ClF}_3 < \text{K}_2\text{O} < \text{LiF}$ (Correct)
  • 2. $2.\ \text{N}_2 > \text{SO}_2 > \text{ClF}_3 > \text{K}_2\text{O} < \text{LiF}$
  • 3. $3.\ \text{N}_2 > \text{SO}_2 > \text{K}_2\text{O} > \text{ClF}_3 > \text{LiF}$
  • 4. $4.\ \text{LiF} > \text{K}_2\text{O} < \text{ClF}_3 > \text{SO}_2 > \text{N}_2$
Solution:
$\text{HINT: Electronegativity difference directly proportional to ionic character.}$ $\text{Explanation:}$ $\text{The greater the electronegativity difference, the greater will be the ionic character of the molecule.}$ $\text{Also, the higher the dipole moment, the higher will be the ionic character e.g. in the case of ClF}_3\text{ the dipole moment is more as compared to SO}_2\text{. Thus, the ionic character of ClF}_3 > \text{SO}_2$. $\text{Electronegativity values of elements:}$ $\text{Li: 0.98}$ $\text{F: 3.98}$ $\text{Cl: 3.16}$ $\text{K: 0.82}$ $\text{O: 3.44}$ $\text{S: 2.58}$ $\text{N: 3.04}$ $\text{Let's calculate the electronegativity difference for each molecule:}$ $\text{LiF: } |3.98 - 0.98| = 3.00$ $\text{K}_2\text{O: For K-O bond, } |3.44 - 0.82| = 2.62$ $\text{N}_2: |3.04 - 3.04| = 0.00$ $\text{SO}_2: \text{For S-O bond, } |3.44 - 2.58| = 0.86$ $\text{ClF}_3: \text{For Cl-F bond, } |3.98 - 3.16| = 0.82$ $\text{Based on electronegativity difference:}$ $\text{N}_2 (0.00) < \text{ClF}_3 (0.82) < \text{SO}_2 (0.86) < \text{K}_2\text{O} (2.62) < \text{LiF} (3.00)$ $\text{Considering the given options and the slight discrepancy for ClF}_3\text{ and SO}_2\text{ in the hint:}$ $\text{The hint states that the ionic character of ClF}_3 > \text{SO}_2\text{ due to dipole moment, even though the electronegativity difference is slightly lower for ClF}_3\text{. This is an important consideration beyond just electronegativity difference, as molecular geometry and lone pairs also contribute to dipole moment.}$ $\text{So, the order based on this revised understanding would be:}$ $\text{N}_2 < \text{SO}_2 < \text{ClF}_3 < \text{K}_2\text{O} < \text{LiF}$ $\text{This matches option 1.}$

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Expected JSON Format:

{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}