Import Question JSON

Current Question (ID: 8037)

Question:
The correct increasing order of bond angles in the following species is:
Options:
  • 1. $\text{Cl}_2\text{O} < \text{ClO}_2 < \text{ClO}_2^-$
  • 2. $\text{ClO}_2^ - < \text{Cl}_2\text{O} < \text{ClO}_2$
  • 3. $\text{Cl}_2\text{O} < \text{ClO}_2^ - < \text{ClO}_2$ (Correct)
  • 4. $\text{ClO}_2^ - < \text{Cl}_2\text{O} < \text{ClO}_2$
Solution:
$\text{HINT: Bond angle } \propto \frac{1}{\text{Number of lone pairs}}$ $\text{Explanation:}$ $\text{As the number of lone pairs of electrons increases, the bond angle decreases due to repulsion between lp-lp. Moreover, as the electronegativity of the central atom decreases, the bond angle decreases.}$ $\text{ClO}_2^ - \text{ (two lone pairs)} < \text{Cl}_2\text{O} \text{ (two lone pairs)} < \text{ClO}_2 \text{ (one lone pair)}$ $\text{Hence, the order of bond angle is } 110^\circ, 111^\circ, 118^\circ$

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Expected JSON Format:

{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}