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Current Question (ID: 10871)

Question:
$\text{Number of monochlorinated products (excluding stereo-isomers) obtained from the given reaction are:}$ $\text{Given compound: 1,3-dimethylcyclohexane undergoes free radical substitution with } \text{Cl}_2/h\nu$
Options:
  • 1. $4$
  • 2. $5$ (Correct)
  • 3. $6$
  • 4. $7$
Solution:
$\text{Hint: Free radical substitution reaction.}$ $\text{When alkane reacts with } \text{Cl}_2 \text{ then a free radical substitution reaction takes place. All the different type of hydrogen in the compound is replaced by chlorine atoms respectively. In this reaction, multiple products are obtained.}$ $\text{The structure of the given compound are as follows:}$ $\text{The compound is 1,3-dimethylcyclohexane with numbered positions showing symmetry.}$ $\text{Positions (1 \& 5), (2 \& 4) and (6 \& 8) are identical positions due to the symmetry of the molecule.}$ $\text{Therefore, five monochlorinated products can be formed and reactions can occur at positions:}$ $\text{1. Positions (1 \& 5) - equivalent due to symmetry}$ $\text{2. Positions (2 \& 4) - equivalent due to symmetry}$ $\text{3. Positions (6 \& 8) - equivalent due to symmetry}$ $\text{4. Position 3 - unique position}$ $\text{5. Position 7 - unique position}$ $\text{The reaction proceeds as follows:}$ $\text{1,3-dimethylcyclohexane } + \text{Cl}_2/h\nu \rightarrow \text{ 5 different monochlorinated products}$ $\text{Each unique hydrogen environment gives rise to one distinct monochlorinated product, excluding stereoisomers.}$ $\text{Therefore, the total number of monochlorinated products (excluding stereo-isomers) is 5.}$

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Expected JSON Format:

{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}