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Current Question (ID: 10917)

Question:
$\text{The major contributor to the resonance hybrid among the following resonance structures is-}$ $\text{(CH)}_3 - \text{(CH)}_2 - \text{CH} - \text{O}::(\text{CH})_3 \leftrightarrow$ $\text{(I)}$ $\text{(CH)}_3 - \text{(CH)}_2 - \text{CH} = \text{O}^\oplus(\text{CH})_3$ $\text{(II)}$
Options:
  • 1. $\text{I}$
  • 2. $\text{II}$ (Correct)
  • 3. $\text{Both have equal contribution}$
  • 4. $\text{They are not resonance structures}$
Solution:
$\text{Hint: If all atoms octet completed thus, it is more stable}$ $\text{The features that decreases the predicted stability of a contributing resonance structure as follows:}$ $\text{1. An atom with an incomplete octet}$ $\text{2. A negative charge that is not on the most electronegative atom or a positive charge that is not on the least electronegative atom}$ $\text{3. Charge separation}$ $\text{In the second structure, all atoms octet is complete. Hence, second structure is the most stable and option two is the correct answer.}$

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Expected JSON Format:

{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}