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Current Question (ID: 17614)

Question:
$\text{The final product in the above sequence of reactions is-}$
Options:
  • 1. $\text{CH}_3\text{COOH}$
  • 2. $\text{CH}_3\text{CH}_2\text{COOH}$
  • 3. $\text{CH}_3\text{CH}_2\text{CH}_2\text{OH}$
  • 4. $\text{HOOC-CH}_2\text{CH}_2\text{CH}_3$
Solution:
$\text{Hint: The fourth reaction is an example of a nucleophilic addition reaction.}$ $\text{In the first reaction, benzene reacts with an acyl chloride in the presence of AlCl}_3 \text{ then a ketone is obtained as a product.}$ $\text{In the second reaction, reduction of ketone takes place and alkylbenzene is obtained as a product.}$ $\text{In the third step, Friedel craft acylation occurs at the para position. In the fourth reaction, cyanohydrin is obtained as a product.}$ $\text{In the final step, hydrolysis of the CN group takes place and the CN group is converted into the COOH group and reduction of the OH group also takes place.}$ $\text{The overall reaction is as follows:}$ $\text{(CH}_3)_2\text{CH-C-Cl} \xrightarrow{\text{AlCl}_3} \text{(CH}_3)_2\text{CH-C=O} \xrightarrow{\text{Clemmensen reduction}} \text{(CH}_3)_2\text{CH-CH}_2\text{Cl} \xrightarrow{\text{AlCl}_3} \text{CH}_3\text{CH}_2\text{CH}_2\text{OH}$

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Expected JSON Format:

{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}