Import Question JSON

Current Question (ID: 17663)

Question:
$[A]$ $\text{and}$ $[B]$ $\text{in the mentioned reaction are respectively:}$
Options:
  • 1. $\text{Alc. KOH and NaNH}_2$
  • 2. $\text{NaNH}_2 \text{and Lindlar catalyst}$
  • 3. $\text{NaNH}_2 \text{and alcoholic KOH}$
  • 4. $\text{Lindlar catalyst and NaNH}_2$
Solution:
$\text{Hint: Ethanolic potassium hydroxide is used to convert terminal triple bond to non-terminal triple bond.}$ $\text{NaNH}_2/\text{liqNH}_3 \text{is used to convert non-terminal triple to terminal triple bond.}$ $\text{CH}_3 - \text{CH} = \text{C} - \equiv \text{C} - \text{H} \xrightarrow{\text{Alc. KOH}} \text{CH}_3 - \text{C} \equiv \text{C} - \text{CH}_3$ $\text{Alc KOH is relatively weak base which abstract H from sp}^3 \text{hybridized carbon}$ $\text{The isomerization of 2-butyne to 1-butyne can be achieved by treatment with NaNH}_2/\text{liqNH}_3.$ $\text{It can be an excellent nucleophile It's used for deprotonation of weak acids}$

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Upload a JSON file containing LaTeX/MathJax formatted question, options, and solution.

Expected JSON Format:

{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}