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Current Question (ID: 18214)

Question:
$\text{Kohlrausch's law states that at:}$
Options:
  • 1. $\text{Finite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte, whatever be the nature of the other ion of the electrolyte.}$
  • 2. $\text{Infinite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte depending on the nature of the other ion of the electrolyte.}$
  • 3. $\text{Infinite dilution, each ion makes definite contribution to conductance of an electrolyte whatever be the nature of the other ion of the electrolyte.}$
  • 4. $\text{Infinite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte, whatever be the nature of the other ion of the electrolyte.}$
Solution:
$\text{Kohlrausch's law states that "at infinite dilution, each ion makes a definite contribution towards equivalent conductance of the electrolyte IRRESPECTIVE of the nature of the other ion with which it is associated. It is due to this reason, it is also called as the law of independent migration of ions."}$ $\text{In other words, equivalent conductivity of an electrolyte at infinite dilution is equal to the sum of the equivalent conductivities of the cation and anion an electrolyte is made up of.}$

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Expected JSON Format:

{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}