Import Question JSON

Current Question (ID: 18303)

Question:
$\text{Select the correct option based on statements below:}$ $\text{Assertion (A): At very high temperatures (approaches to infinity), the rate}$ $\text{constant becomes equal to the collision frequency.}$ $\text{Reason (R): The collision in which molecules collide with proper orientation}$ $\text{is called an ineffective collision.}$
Options:
  • 1. $\text{Both (A) and (R) are true and (R) is the correct explanation of (A).}$
  • 2. $\text{Both (A) and (R) are true but (R) is not the correct explanation of (A).}$
  • 3. $\text{(A) is true but (R) is false.}$
  • 4. $\text{Both (A) and (R) are false.}$
Solution:
$\text{HINT: Rate = } Z_{AB} e^{-E_a/RT}$ $\text{Explanation:}$ $\text{At very high temperature (approaches to infinity) rate constant becomes}$ $\text{equal to collision frequency because}$ $\text{rate = } Z_{AB} e^{-E_a/RT} , \text{ when T trends to infinity } e^{-E_a/RT} \text{ became one, and rate = } Z_{AB}.$ $\text{The collision in which molecules collide with proper orientation is called an}$ $\text{effective collision. Hence, Assertion is a true statement but the reason is}$ $\text{false.}$

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Expected JSON Format:

{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}