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Current Question (ID: 18824)

Question:
$\text{The increasing order of oxidising power among the following species is:}$
Options:
  • 1. $\text{VO}_2^+ < \text{Cr}_2\text{O}_7^{2-} < \text{MnO}_4^-$
  • 2. $\text{VO}_2^+ < \text{MnO}_4^- < \text{Cr}_2\text{O}_7^{2-}$
  • 3. $\text{Cr}_2\text{O}_7^{2-} < \text{VO}_2^+ < \text{MnO}_4^-$
  • 4. $\text{Cr}_2\text{O}_7^{2-} < \text{MnO}_4^- < \text{VO}_2^+$
Solution:
$\text{HINT: Oxidising power } \propto \text{ Oxidation state.}$ $\text{Explanation:}$ $\text{Oxidising power is directly proportional to the oxidation state of central atom in a molecule.}$ $\text{The order is as follows:}$ $\text{VO}_2^+ < \text{Cr}_2\text{O}_7^{2-} < \text{MnO}_4^-$ $\text{Oxidation state of V in } \text{VO}_2^+ \text{ is } +5.$ $\text{Oxidation state of Cr in } \text{Cr}_2\text{O}_7^{2-} \text{ is } +6$ $\text{Oxidation state of Mn in } \text{MnO}_4^- \text{ is } +7$

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Expected JSON Format:

{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}