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Current Question (ID: 19581)

Question:
$\text{A large number of water drops, each of radius } r, \text{ combine to have a drop of radius } R. \text{ If the surface tension is } T \text{ and mechanical equivalent of heat is } J, \text{ the rise in heat energy per unit volume will be:}$
Options:
  • 1. $\frac{2T}{J} \left( \frac{1}{r} - \frac{1}{R} \right)$
  • 2. $\frac{2T}{Jr}$
  • 3. $\frac{3T}{Jr}$
  • 4. $\frac{3T}{J} \left( \frac{1}{r} - \frac{1}{R} \right)$
Solution:
$\text{Hint: Work done = surface tension } \times \text{ change in surface area.}$ $\text{Step 1: Find the change in the surface energy.}$ $\text{The surface area of a single small drop is given by:}$ $\Rightarrow A_{\text{small}} = 4\pi r^2$ $\text{Suppose there are } n \text{ such small drops, then the total surface area of these small drops is given by:}$ $\Rightarrow A_{\text{total small}} = n \times 4\pi r^2$ $\text{Since the total volume remains constant, we use volume conservation:}$ $\Rightarrow n \times \frac{4}{3} \pi r^3 = \frac{4}{3} \pi R^3 \Rightarrow n = \frac{R^3}{r^3}$ $\text{The surface area of the final large drop is given by:}$ $\Rightarrow A_{\text{large}} = 4\pi R^2$ $\text{The initial surface energy is given by:}$ $\Rightarrow U_{\text{initial}} = \text{surface tension } \times \text{ total initial surface area} = T \times n \times 4\pi r^2$ $\text{The final surface energy is given by:}$ $\Rightarrow U_{\text{final}} = T \times 4\pi R^2$ $\text{The decrease in surface energy (converted to heat) is given by:}$ $\Delta U = U_{\text{initial}} - U_{\text{final}} = 4\pi T \frac{R^3}{r} - 4\pi T R^2 \Rightarrow 4\pi T R^2 \left( \frac{R}{r} - 1 \right)$ $\text{Step 2: Find the heat energy per unit volume.}$ $\text{This energy is converted to heat, and using the mechanical equivalent of heat } J, \text{ the heat energy released per unit volume is given by:}$ $\Rightarrow \frac{\Delta U}{\text{Volume}} = \frac{4\pi T R^2 \left( \frac{R}{r} - 1 \right)}{\frac{4}{3} \pi R^3} = \frac{3T}{R} \left( \frac{R}{r} - 1 \right)$ $\Rightarrow \frac{\Delta U}{\text{Volume}} = \frac{3T}{J} \left( \frac{1}{r} - \frac{1}{R} \right)$ $\text{Hence, option (4) is the correct answer.}$

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Expected JSON Format:

{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}