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Current Question (ID: 21287)

Question:
$\text{In the Carius method for estimation of halogens, 180 mg of an organic compound produced 143.5 mg of AgCl. The percentage composition of chlorine in the compound is:}$ $\text{[Given: molar mass in g mol}^{-1} \text{ of Ag and Cl are 108, 35.5 respectively]}$
Options:
  • 1. $27.91\%$
  • 2. $46.32\%$
  • 3. $19.72\%$
  • 4. $59.67\%$
Solution:
$\text{Hint: } \% \text{ of Cl} = \frac{35.5}{143.5} \times \frac{\text{Mass of AgCl formed}}{\text{Mass of substance taken}} \times 100$ $n_{\text{Cl}} = n_{\text{AgCl}} = \frac{143.5 \times 10^{-3}}{143.5} = 10^{-3}$ $\% \text{Cl} = \frac{10^{-3} \times 35.5}{180 \times 10^{-3}} \times 100 = 19.72$

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Expected JSON Format:

{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}