Import Question JSON

Current Question (ID: 7464)

Question:
$\text{The electron of a Br atom that experiences the lowest effective nuclear charge is:}$
Options:
  • 1. $2p \text{ and } 3p$
  • 2. $4p$
  • 3. $2p$
  • 4. $3p$
Solution:
$\text{Hint: The order of shielding effect is s orbitals > p orbitals > d orbitals > f orbitals.}$ $\text{Explanation:}$ $\text{As the distance increases, the effective nuclear charge also decreases.}$ $\text{Bromine has atomic number 35, so it has a nuclear charge of +35.}$ $\text{The electronic configuration of Br is: } 1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^{10} 4p^5$ $\text{Among p-orbitals, 4p orbitals are farthest from the nucleus of the bromine atom.}$ $\text{The electrons in the 4p orbital experience the most shielding because:}$ $\text{- They are shielded by all inner electrons (1s, 2s, 2p, 3s, 3p, 4s, 3d)}$ $\text{- They are in the outermost shell and farthest from the nucleus}$ $\text{Hence, the electrons in the 4p orbital will experience the lowest effective nuclear charge.}$ $\text{These electrons are shielded by electrons present in the 2p and 3p orbitals along with the s-orbitals.}$ $\text{Therefore, 4p electrons experience the lowest effective nuclear charge.}$

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Expected JSON Format:

{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}