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Current Question (ID: 8291)

Question:
$\text{An ideal gas expands isothermally from } 10^{-3}m^3 \text{ to } 10^{-2} m^3 \text{ at 300 K against a constant pressure of } 10^5 \text{ Nm}^{-2}\text{. The work done by the gas is:}$
Options:
  • 1. $+270 \text{ kJ}$
  • 2. $-900 \text{ J}$
  • 3. $+900 \text{ kJ}$
  • 4. $-900 \text{ kJ}$
Solution:
$\text{Hint: Use work done formula}$ $\text{Step 1: Identify the type of process and the appropriate formula}$ $\text{The problem describes an isothermal expansion against a constant external pressure. Since the pressure is constant, we can use the formula:}$ $W = -P_{\text{ext}}\Delta V$ $\text{Where:}$ $P_{\text{ext}} = \text{external pressure} = 10^5 \text{ N/m}^2$ $\Delta V = V_f - V_i = \text{change in volume}$ $\text{Step 2: Calculate the change in volume}$ $V_i = 10^{-3} \text{ m}^3 \text{ (initial volume)}$ $V_f = 10^{-2} \text{ m}^3 \text{ (final volume)}$ $\Delta V = V_f - V_i = 10^{-2} - 10^{-3} = 9 \times 10^{-3} \text{ m}^3 = 0.009 \text{ m}^3$ $\text{Step 3: Calculate the work done by the gas}$ $W = -P_{\text{ext}}\Delta V$ $W = -10^5 \times [10^{-2} - 10^{-3}]$ $W = -10^5 \times 0.009$ $W = -900 \text{ J}$ $\text{The negative sign indicates that the gas is doing work on the surroundings during expansion.}$ $\text{Step 4: Verify the units and magnitude}$ $\text{The units are correct: N/m}^2 \times \text{m}^3 = \text{N} \cdot \text{m} = \text{J (joules)}$ $\text{The work done by the gas is -900 J, which corresponds to option 2.}$ $\text{Note: It's important to recognize that in thermodynamics, work done by a system (in this case, the gas) on the surroundings is conventionally given a negative sign. The gas is expanding and pushing against the external pressure, so it is doing work on the surroundings.}$

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Expected JSON Format:

{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}