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Current Question (ID: 8315)
Question:
$\text{The bond energy of H}−\text{H and Cl-Cl is } 430 \text{ kJ mol}^{-1} \text{ and } 240 \text{ kJ mol}^{-1} \text{ respectively}$
$\text{and } \Delta H_f \text{ for HCl is } -90 \text{ kJ mol}^{-1}\text{. The bond enthalpy of HCl is:}$
Options:
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1. $290 \text{ kJ mol}^{-1}$
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2. $380 \text{ kJ mol}^{-1}$
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3. $425 \text{ kJ mol}^{-1}$
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4. $245 \text{ kJ mol}^{-1}$
Solution:
$\text{Hint: } \Delta\text{H}_f = \sum \text{BE}_R - \sum \text{BE}_P$
$\text{Step 1: Write the balanced equation for the formation of HCl}$
$\text{H}_2 + \text{Cl}_2 \rightarrow 2 \text{ HCl}$
$\text{Step 2: Apply the relationship between enthalpy of formation and bond energies}$
$\text{Using the equation: } \Delta\text{H}_f = \sum \text{Bond Energies (reactants)} - \sum \text{Bond Energies (products)}$
$\text{For the given reaction:}$
$\Delta\text{H}_f = \text{BE}_{\text{H-H}} + \text{BE}_{\text{Cl-Cl}} - 2 \times \text{BE}_{\text{H-Cl}}$
$\text{Rearranging to find BE}_{\text{H-Cl}}\text{:}$
$\text{BE}_{\text{H-Cl}} = \frac{\text{BE}_{\text{H-H}} + \text{BE}_{\text{Cl-Cl}} - \Delta\text{H}_f}{2}$
$\text{Step 3: Substitute the given values}$
$\text{BE}_{\text{H-Cl}} = \frac{430 \text{ kJ mol}^{-1} + 240 \text{ kJ mol}^{-1} - (-90 \text{ kJ mol}^{-1} \times 2)}{2}$
$\text{BE}_{\text{H-Cl}} = \frac{430 \text{ kJ mol}^{-1} + 240 \text{ kJ mol}^{-1} + 180 \text{ kJ mol}^{-1}}{2}$
$\text{BE}_{\text{H-Cl}} = \frac{850 \text{ kJ mol}^{-1}}{2} = 425 \text{ kJ mol}^{-1}$
$\text{Therefore, the bond enthalpy of HCl is } 425 \text{ kJ mol}^{-1}$
$\text{Note: There is a calculation error in the solution image. The value of } \Delta\text{H}_f \times 2 = -90 \times 2 = -180 \text{ kJ mol}^{-1}\text{, which when moved to the right side of the equation becomes } +180 \text{ kJ mol}^{-1}\text{. The numerator should be } 430 + 240 + 180 = 850 \text{ kJ mol}^{-1}\text{, giving a bond enthalpy of } 425 \text{ kJ mol}^{-1}\text{.}$
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