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Current Question (ID: 8315)

Question:
$\text{The bond energy of H}−\text{H and Cl-Cl is } 430 \text{ kJ mol}^{-1} \text{ and } 240 \text{ kJ mol}^{-1} \text{ respectively}$ $\text{and } \Delta H_f \text{ for HCl is } -90 \text{ kJ mol}^{-1}\text{. The bond enthalpy of HCl is:}$
Options:
  • 1. $290 \text{ kJ mol}^{-1}$
  • 2. $380 \text{ kJ mol}^{-1}$
  • 3. $425 \text{ kJ mol}^{-1}$
  • 4. $245 \text{ kJ mol}^{-1}$
Solution:
$\text{Hint: } \Delta\text{H}_f = \sum \text{BE}_R - \sum \text{BE}_P$ $\text{Step 1: Write the balanced equation for the formation of HCl}$ $\text{H}_2 + \text{Cl}_2 \rightarrow 2 \text{ HCl}$ $\text{Step 2: Apply the relationship between enthalpy of formation and bond energies}$ $\text{Using the equation: } \Delta\text{H}_f = \sum \text{Bond Energies (reactants)} - \sum \text{Bond Energies (products)}$ $\text{For the given reaction:}$ $\Delta\text{H}_f = \text{BE}_{\text{H-H}} + \text{BE}_{\text{Cl-Cl}} - 2 \times \text{BE}_{\text{H-Cl}}$ $\text{Rearranging to find BE}_{\text{H-Cl}}\text{:}$ $\text{BE}_{\text{H-Cl}} = \frac{\text{BE}_{\text{H-H}} + \text{BE}_{\text{Cl-Cl}} - \Delta\text{H}_f}{2}$ $\text{Step 3: Substitute the given values}$ $\text{BE}_{\text{H-Cl}} = \frac{430 \text{ kJ mol}^{-1} + 240 \text{ kJ mol}^{-1} - (-90 \text{ kJ mol}^{-1} \times 2)}{2}$ $\text{BE}_{\text{H-Cl}} = \frac{430 \text{ kJ mol}^{-1} + 240 \text{ kJ mol}^{-1} + 180 \text{ kJ mol}^{-1}}{2}$ $\text{BE}_{\text{H-Cl}} = \frac{850 \text{ kJ mol}^{-1}}{2} = 425 \text{ kJ mol}^{-1}$ $\text{Therefore, the bond enthalpy of HCl is } 425 \text{ kJ mol}^{-1}$ $\text{Note: There is a calculation error in the solution image. The value of } \Delta\text{H}_f \times 2 = -90 \times 2 = -180 \text{ kJ mol}^{-1}\text{, which when moved to the right side of the equation becomes } +180 \text{ kJ mol}^{-1}\text{. The numerator should be } 430 + 240 + 180 = 850 \text{ kJ mol}^{-1}\text{, giving a bond enthalpy of } 425 \text{ kJ mol}^{-1}\text{.}$

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{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}