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Current Question (ID: 8582)

Question:
$ \text{Which of the following is not an intramolecular redox reaction?} $
Options:
  • 1. $ \text{NH}_4\text{NO}_2 \rightarrow \text{N}_2 + 2\text{H}_2\text{O} $
  • 2. $ 2\text{Mn}_2\text{O}_7 \rightarrow 4\text{MnO}_2 + 3\text{O}_2 $
  • 3. $ 2\text{KClO}_3 \rightarrow 2\text{KCl} + 3\text{O}_2 $
  • 4. $ 2\text{H}_2\text{O}_2 \rightarrow 2\text{H}_2\text{O} + \text{O}_2 $
Solution:
\text{Hint: Intramolecular redox change involve oxidation of one atom and reduction of another atom within a molecule.} \\ \text{NH}_4\text{NO}_2 \rightarrow \text{N}_2 + 2\text{H}_2\text{O} \\ \text{(-3)} \quad \text{(+3)} \quad \text{(0)} \\ \text{oxidation} \quad \text{reduction} \\ \text{Mn}_2\text{O}_7 \rightarrow \text{MnO}_2 + 3\text{O}_2 \\ \text{(+7)} \quad \text{(-2)} \quad \text{(+4)} \quad \text{(0)} \\ \text{reduction} \quad \text{oxidation} \\ \text{KClO}_3 \rightarrow 2\text{KCl} + 3\text{O}_2 \\ \text{(+5)} \quad \text{(-2)} \quad \text{(-1)} \quad \text{(0)} \\ \text{reduction} \quad \text{oxidation} \\ \text{H}_2\text{O}_2 \rightarrow 2\text{H}_2\text{O} + \text{O}_2 \\ \text{(-1)} \quad \text{(-2)} \quad \text{(0)} \\ \text{reduction} \quad \text{oxidation} \\ \text{In 1st case its one N, with +3 state undergoes reduction, where as another nitrogen with -3 undergoes oxidation, its not a disproportionation reaction because in that case reactant atom must have one oxidation state.} \\ \text{In 2nd case, its Mn which undergoes reduction and O which undergoes oxidation.} \\ \text{In 3rd case - its Cl which undergoes reduction and O undergoes oxidation.} \\ \text{Where as in 4th case, its O of H}_2\text{O}_2 \text{ which undergoes oxidation as well as reduction, so it will be a disproportionation reaction}

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{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}