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Current Question (ID: 8600)
Question:
$\text{The oxidation state of Cr in } \text{CrO}_6 \text{ is -}$
Options:
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1. $-6$
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2. $+12$
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3. $+6$
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4. $+4$
Solution:
$\text{Hint: Maximum oxidation state of Cr is } +6\text{.}$
$\text{Explanation:}$
$\text{Step 1: Initial calculation of oxidation state}$
$\text{Assume the typical oxidation state of oxygen is } -2\text{.}$
$\text{Let the oxidation state of Cr be } x\text{.}$
$x + 6 \times (-2) = 0$
$x - 12 = 0$
$x = +12$
$\text{Step 2: Check for abnormality and presence of peroxide linkage.}$
$\text{The maximum oxidation number shown by Chromium (Cr) is } +6\text{. Since the calculated oxidation number of Cr in } \text{CrO}_6 \text{ is } +12\text{, which is greater than its maximum possible oxidation state, this indicates that } \text{CrO}_6 \text{ contains peroxide linkages.}$
$\text{Step 3: Calculate the number of peroxide bonds.}$
$\text{Number of peroxide bonds} = \frac{\text{Calculated oxidation number} - \text{Maximum oxidation number}}{2}$
$\text{Number of peroxide bonds} = \frac{+12 - +6}{2} = \frac{6}{2} = 3$
$\text{This means there are three peroxide linkages in } \text{CrO}_6\text{.}$
$\text{The structure of } \text{CrO}_6 \text{ is as follows:}$
$\text{It has a structure where the central Cr atom is bonded to three } \text{O}_2 \text{ units (peroxide groups) and two single oxygen atoms forming a ring, or more commonly described as having three peroxide bridges.}$
$\text{In this structure, there are three peroxide linkages (-O-O-) and no oxygen atoms with an oxidation state of } -2\text{. Each oxygen atom in a peroxide linkage has an oxidation state of } -1\text{.}$
$\text{Recalculate the oxidation state of Cr based on the peroxide structure:}$
$\text{Let the oxidation state of Cr be } X\text{.}$
$\text{There are } 6 \text{ oxygen atoms in } \text{CrO}_6\text{. If there are three peroxide linkages, all } 6 \text{ oxygen atoms are involved in these linkages, meaning their oxidation state is } -1\text{.}$
$X + 6 \times (-1) = 0$
$X - 6 = 0$
$X = +6$
$\text{Hence, the oxidation number of Cr in } \text{CrO}_6 \text{ is } +6\text{.}$
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