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Current Question (ID: 9145)

Question:
$\text{The correct order of increasing thermal stability of } \text{K}_2\text{CO}_3\text{, } \text{MgCO}_3\text{, } \text{CaCO}_3 \text{ and } \text{BeCO}_3 \text{ is:}$
Options:
  • 1. $\text{BeCO}_3 < \text{MgCO}_3 < \text{K}_2\text{CO}_3 < \text{CaCO}_3$
  • 2. $\text{BeCO}_3 < \text{MgCO}_3 < \text{CaCO}_3 < \text{K}_2\text{CO}_3$
  • 3. $\text{MgCO}_3 < \text{BeCO}_3 < \text{CaCO}_3 < \text{K}_2\text{CO}_3$
  • 4. $\text{K}_2\text{CO}_3 < \text{MgCO}_3 < \text{CaCO}_3 < \text{BeCO}_3$
Solution:
$\text{Hint: Thermal stability increases with increasing cationic size.}$ $\text{Explanation:}$ $\text{Thermal stability of carbonates increases down the group and decreases left to right in a period.}$ $\text{As the positive ions get larger down the group, they affect on the carbonate ions near them less. More heat must be supplied for the carbon dioxide to leave the metal oxide.}$ $\text{In other words, the carbonates become more thermally stable down the group. So, the correct order of thermal stability of given carbonates is:}$ $\text{BeCO}_3 < \text{MgCO}_3 < \text{CaCO}_3 < \text{K}_2\text{CO}_3$

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Expected JSON Format:

{
  "question": "The mass of carbon present in 0.5 mole of $\\mathrm{K}_4[\\mathrm{Fe(CN)}_6]$ is:",
  "options": [
    {
      "id": 1,
      "text": "1.8 g"
    },
    {
      "id": 2,
      "text": "18 g"
    },
    {
      "id": 3,
      "text": "3.6 g"
    },
    {
      "id": 4,
      "text": "36 g"
    }
  ],
  "solution": "\\begin{align}\n&\\text{Hint: Mole concept}\\\\\n&1 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\text{ moles of carbon atom}\\\\\n&0.5 \\text{ mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6] = 6 \\times 0.5 \\text{ mol} = 3 \\text{ mol}\\\\\n&1 \\text{ mol of carbon} = 12 \\text{ g}\\\\\n&3 \\text{ mol carbon} = 12 \\times 3 = 36 \\text{ g}\\\\\n&\\text{Hence, 36 g mass of carbon present in 0.5 mole of } \\mathrm{K}_4[\\mathrm{Fe(CN)}_6].\n\\end{align}",
  "correct_answer": 4
}